Journal of Geosciences and Geomatics. 2020, 8(1), 1-8
DOI: 10.12691/JGG-8-1-1
Original Research

Secondary Enrichment of Ferriferous Pre-Cambrian Quartzites by Meteorical Weathering in South Cameroon

Bidjo Emvoutou Gery Christian1, 2, Ndzie Mvondo Justin3, 2, , Ngo Bidjeck Louise Marie2, Ipan Antoinnette1, 2, Ntomb Yvan Demonstel1, 2 and Ndong Bidzang Francois3

1Centre for Geological and Mining Research, P.O. Box: 333, Garoua, Cameroon

2Department of Earth Sciences, University of Yaoundé I, P.O. Box: 812, Yaoundé, Cameroon

3Ore Processing Laboratory, Institute for Geological and Mining Research, P.O. Box: 4110Yaounde, Cameroon

Pub. Date: January 19, 2020

Cite this paper

Bidjo Emvoutou Gery Christian, Ndzie Mvondo Justin, Ngo Bidjeck Louise Marie, Ipan Antoinnette, Ntomb Yvan Demonstel and Ndong Bidzang Francois. Secondary Enrichment of Ferriferous Pre-Cambrian Quartzites by Meteorical Weathering in South Cameroon. Journal of Geosciences and Geomatics. 2020; 8(1):1-8. doi: 10.12691/JGG-8-1-1

Abstract

The meteoric weathering of Precambrian ferriferous quartzites from Meyomessi in southern Cameroon has led, in a humid tropical climate, to the formation of secondary oxidized ores. The weathering profile of the ferriferous quartzites shows from the base to the summit: the bedrock, the saprolites, the gravel horizon and a surface sandy clayey aggregate, ferriferous quartzite is a finely banded rock showing alternating quartz beds and iron oxide beds. The main features of the Meyomessi quartzite geochemistry show that the ferruginous facies are remarkably poor in any element other than Fe and Si. The alteration of the materials shows high Fe, Si, Al, Cr, Zr, Ba, Ga, Nb and Th. Rare earth elements levels are generally low compared to Ce, La and Nd, which are concentrated in upper gravel and sandy-clay levels. The rare earth elements spectrum indicates a positive anomaly in Ce and a negative anomaly in Eu. The results obtained from the calculated balances show a very high enrichment in Al, Ti and K in all the altered materials, low in Si and P in the higher levels and weak in iron in the weathered fragments and in the sandy clay loam level. The losses are total and moderate for all the trace elements, while the rare earths elements are enriched in the soft materials of the whole profile. The iron content in the bedrock (64.9%) versus 68% in the weathered rock fragments (ore), shows that the climatic alteration improves the quality of the ore in the ferruginous fragments by dissolution of the silica and relative concentration iron.

Keywords

meteorological weathering, ferriferous quartzites, Meyomessi, enrichment

Copyright

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References

[1]  Chombong, N.N., Suh, C.E., 2013. 2883 Ma commencement of BIF deposition at the northern edge of Congo craton, southern Cameroon: new zircon SHRIMP data constraint from metavolcanics. Episodes 36, 47-57.
 
[2]  Ganno S., Ngnotue, T., Kouankap Nono, G.D., Nzenti, J.P., Notsa, F.M., 2015. Petrology and geochemistry of the banded iron-formations from Ntem complex greenstones belt, Elom area, Southern Cameroon: implications for the origin and depositional environment. Chem. Erde 75, 375-387.
 
[3]  Ilouga, C.D.I., Suh, C.E., Ghogomu, R.T., 2013. Textures and rare earth elements composition of Banded Iron Formations (BIF) at Njweng prospect, Mbalam Iron Ore District, Southern Cameroon. Int. J. Geosci. 4, 146-165.
 
[4]  Ndong Bidzang Francois, Sobdjou Kemteu Christel, Mero Yannah, Ntomba Martial Sylvestre, Nzenti Jean Paul, Mvondo Ondoa Joseph. Origin and Tectonic Framework of the Ngovayang Iron Massifs, South Cameroon. Science Research. Vol. 4, No. 1, 2016, pp. 11-20.
 
[5]  Nsoh, F.E., Agbor, T.A., Etame, J., Suh, E.C., 2014. Ore-textures and geochemistry of the Nkout iron deposit South East Cameroon. Sciences. Technol. Dév. 15, 43-52.
 
[6]  Ramanaïdou, E(1989). Genèse d’un gisement latéritique. Evolution supergène des itabirites protérozoïques de la mine de Capanema (Minas Gerais, Brésil). Th. Doc., Univ. Poitiers, 183p.
 
[7]  Eno Belinga S. M. (1986). Il y’a 600 millions d’années…métaux, non métaux et substances utiles du Cameroun. C.E.P.E.R., 128p.
 
[8]  Lasserre M. et D. Soba (1976). Migmatisation d’âge panafricain au sein des formations Camerounaises appartenant à la zone mobile de l’Afrique Centrale. C.R. Somm. Soc. Géol. Fr., 2p. 64-68.
 
[9]  Toteu, S. M., Van Schmus, W. R., Penaye, J., and Nyobé, J. B. (1994). U-Pb and Sm-Nd evidence of eburnean and pan African high grade metamorphism in cratonic rock of southern Cameroon. Precambrian Research Vol. 67: 321-347.
 
[10]  Shang, C.K., Liégeois, J.-P., Satir, M., Nsifa, E.N., 2010. Late Archaean high-K granite geochronology of the northern metacratonic margin of the Archaean Congo craton. Southern Cameroon: evidence for Pb-loss due to non-metamorphic causes. Gondwana Research 18, 337-355.
 
[11]  Owona, S. Mvondo Ondoa, J. Ratschbacher, L. Mbola Ndzana, S.P. Tchoua, M.F. & Ekodeck, G.E. 2011. The geometry of the Archean, Paleo- and Neoproterozoic tectonics in the Southwest Cameroon. Comptes Rendus Geosciences, 343: 312-322.
 
[12]  Shang, C.K., Siebel, W., Satir, M., Chen, F., Mvondo Ondoua, J., 2004. Zircon Pb–Pb and U–Pb systematics of TTG rocks in the Congo Craton: constraints on crust formation, magmatism, and Pan-African lead loss. Bulletin of Geosciences 79 (4), 205-219.
 
[13]  Ledru, P., Johan, V., Mile´si, J.P., Tegyey, M., 1994. Markers of the last stages of the Palaeoproterozoic collision: evidence for a 2 Ga continent involving circum-South Atlantic provinces. Precamb. Res. 69,169-191.
 
[14]  S. M. Ntomba, F. Ndong Bidzang, J. E. Messi Ottou, François, J. Goussi Ngalamo, D. Bisso, Christelle R. Magnekou Takamte, J. Mvondo Ondoa. Phlogopite compositions as an indicator of both the geodynamic context of granitoids and the metallogeny aspect in Memve'ele Archean area, northwestern Congo craton. Journal of African Earth Sciences 118 (2016) 231-244.
 
[15]  Nsifa, N. E., Tchameni, R., Nédélec, A., Siqueira, R., Pouclet, A., Bascou, J., 2013. Structure and petrology of Pan-African nepheline syenites from the South West Cameroon; Implications for their emplacement mode, petrogenesis and geodynamic significance. Journal of African Earth Sciences 87, 44-58.
 
[16]  Nédélec, A., Nsifa, E.N., Martin, H. (1990). Major and trace element geochemistry of the Archean Ntem plutonic complex (South Cameroon) :petrogenesis and crustal evolution provenance of detritus for the Nyong Group. Precambrian Research Vol.47: 35-50.
 
[17]  Nedelec, A. et Nsifa, E. N., 1987. Le complexe du Ntem (Sud-Cameroun): une série tonalito-trondhjémitique archéen typique. Cur. Reaserch. In Africa. Earth Sc. Matheis and Schandelmeier (eds), pp 3-6.
 
[18]  Kurtz, A.C., Derry, L.A., Chadwick, O.A., Alfano, M.J., 2000. Refractory element mobility in volcanic soils. Geology 28 (8), 683-686.
 
[19]  Braun, J.-J., Viers, J., Drupre, B., Polve, M, Ndam, J.R., Muller, J.-P. (1993). Solid/liquid REE fractionation in the lateritic system of Goyoum, East Cameroun: The Geochim. Cosmochim. Acta 62, 2, 273-299.
 
[20]  Ilouga, D. C. I., Suh C. E., Tanwi G. R. (2013). Textures and Rares Earth Elements Composition ozvf Banded Iron Formations (BIF) at Njweng Prospect, Mbalam Iron Ore District, Southern Cameroon. International Journal of Geosciences, 4, pp146-165.
 
[21]  Ngo Bidjeck, L.M., 2004. L’altération des roches basiques et ultrabasiques du Sud-Ouest Cameroun et ses implications métallogéniques. Cas du complexe d’Abiété-Yenjok. Thèse de Doct. /Ph.D, Univ. de Yaoundé I, 267 p.
 
[22]  Duchaufour, P. (1978). Ecological Atlas of Soils of the World. 1978 pp.178 pp.
 
[23]  Blot A, C m M, Leprun JC et Pion JC, 1976, Premier bilan des études géologiques et pédologiques d'un corps ultra basique et de son contexte : Koussâne au Sénégal Oriental . CA. ORSTOM sér. Geel., vol VI11 , n02,113-145.
 
[24]  Manikyamba, C., Naqvi, S.M., 1995. Geochemistry of Fe–Mn formations in the Archean Sandur schist belt, India: mixing of clastic and chemical processes at a shallow shelf. Precambrian Res. 72, 69-95.
 
[25]  Pelletier, B. (1983). Localisation du nickel dans les minerais « garniéritiques » de Nouvelle -Calédonie. Sci. Geol. Mem, 73. P173-183.
 
[26]  Duddy, I. R. (1980). Redistribution and fractionation of rare earth and other elements in weathering profile. Chem. Geol. 30, 363-381.
 
[27]  S.E. Topp, B. Salbu, E. Roaldset, P. Jørgensen, 1984. Vertical distribution of trace elements in laterite soil (Suriname). Chemical Geology Pages 159-174.
 
[28]  Braun I (1999) Generation of leucogranites in the Kerala Khondalite Belt, southern India. Phys Chem Earth (A) 24: 281-287.
 
[29]  Jean Braun; Christopher Beaumont, 1989. A physical explanation of the relation between flank uplifts and the breakup unconformity at rifted continental margins. Geology (1989) 17 (8): 760-764.
 
[30]  Brokins, D.G. (1988). Eh-Ph diagrams for Geochemistry, Springer-Verlang, Berlin Heidelberg.
 
[31]  Leleyter, L., Probst, J.L., Depetris, P., Haida, S., Mortatti, J., Rouault, J., Samuel, J. (1999). REE redistribution and labile fractions C.R. Acad. Sci.ParisSer. IIa 329. 45-52.
 
[32]  Piper, 1974. Rare earth elements in the sedimentary cycle: A summary. Chemical Geology Pages 285-304.
 
[33]  Aagaard, P. (1974). Rare earth absorption on clay minerals.Bull. Groupe Fr. argiles 26, 193-199.
 
[34]  E. Roaldset, 1974. Lanthanide distributions in clays. Bull. Groupe franc. Argile. tXXVI, pp. 201-209.
 
[35]  Matthew I. Leybourne, Eion M. Cameron, 2006. Composition of Soils and Ground Waters at the Pampa del Tamarugal, Chile: Anatomy of a Fossil Geochemical Anomaly Derived from a Distant Porphyry Copper Deposit. Economic Geology (2006) 101 (8): 1569-1581.
 
[36]  Braun, J.-J., Viers, J., Dupre´, B., Polve, M., Ndam, J., Muller, J.P., 1998.Solid/liquid REE fractionation in the lateritic system of Goyoum, East Cameroon: the implication for the present dynamics of the soil covers of the humid tropical regions. Geochim. Cosmochim. Acta 62 (2), 273-299.
 
[37]  Mc Murry Je; Miller Dd, 1983. Synthesis Of Isocaryophyllene By Titanium-Induced Keto Ester Cyclization. Tetrahedron Letters; Issn 0040-4039; Gbr; Da. 1983; Vol. 24; No 18; Pp. 1885-1888; Bibl. 8 Ref.
 
[38]  James L. Jerden Jr, A.KSinha, 2003. Phosphate based immobilization of uranium in an oxidizing bedrock aquifer. Applied Geochemistry, Elsevier Science Volume 18, Issue 6, June 2003, Pages 823-843.